Magnet wire or enameled wire is a copper or aluminum wire coated with a very thin layer of insulation. It is used in the construction of transformers, inductors, motors, generators, speakers, hard disk head actuators, electromagnets, electric guitar pickups and other applications that require tight coils of insulated wire.

The wire itself is most often fully annealed, electrolytically refined copper. Aluminum magnet wire is sometimes used for large transformers and motors. The insulation is typically made of tough polymer film materials rather than enamel, as the name might suggest.

Conductor
The most suitable materials for magnet wire applications are unalloyed pure metals, particularly copper. When factors such as chemical, physical, and mechanical property requirements are considered, copper is considered the first choice conductor for magnet wire.

Most often, magnet wire is composed of fully annealed, electrolytically refined copper to allow closer winding when making electromagnetic coils. High-purity oxygen-free copper grades are used for high-temperature applications in reducing atmospheres or in motors or generators cooled by hydrogen gas.

Aluminium magnet wire is sometimes used as an alternative for large transformers and motors. Because of its lower electrical conductivity, aluminium wire requires a 1.6-times larger cross sectional area than a copper wire to achieve comparable DC resistance.

Insulation

Although described as "enameled", enameled wire is not, in fact, coated with a layer of enamel paint or vitreous enamel made of fused glass powder. Modern magnet wire typically uses one to four layers (in the case of quad-film type wire) of polymer film insulation, often of two different compositions, to provide a tough, continuous insulating layer. Magnet wire insulating films use (in order of increasing temperature range) polyvinyl formal (Formvar), polyurethane, polyamide, polyester, polyester-polyimide, polyamide-polyimide (or amide-imide), and polyimide. Polyimide insulated magnet wire is capable of operation at up to 250 °C. The insulation of thicker square or rectangular magnet wire is often augmented by wrapping it with a high-temperature polyimide or fiberglass tape, and completed windings are often vacuum impregnated with an insulating varnish to improve insulation strength and long-term reliability of the winding.

Self-supporting coils are wound with wire coated with at least two layers, the outermost being a thermoplastic that bonds the turns together when heated.

Other types of insulation such as fiberglass yarn with varnish, aramid paper, kraft paper, mica, and polyester film are also widely used across the world for various applications like transformers and reactors. In the audio sector, a wire of silver construction, and various other insulators, such as cotton (sometimes permeated with some kind of coagulating agent/thickener, such as beeswax) and polytetrafluoroethylene (Teflon) can be found. Older insulation materials included cotton, paper, or silk, but these are only useful for low-temperature applications (up to 105°C).

For ease of manufacturing, some low-temperature-grade magnet wire has insulation that can be removed by the heat of soldering. This means that electrical connections at the ends can be made without stripping off the insulation first.