China Factory Supply Good Prices Pigment Powder Yellow 138, Find details about China Ferric Oxide, Oxide from Factory Supply Good Prices Pigment Powder Yellow 138
Names | |
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IUPAC name Iron(III) oxide | |
Other names ferric oxide, hematite, ferric iron, red iron oxide, rouge, maghemite, colcothar, iron sesquioxide, rust, ochre | |
Identifiers | |
CAS Number |
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3D model (JSmol) |
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ChEBI |
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ECHA InfoCard | 100.013.790 |
EC Number |
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E number | E172(ii) (colours) |
Gmelin Reference | 11092 |
RTECS number |
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Properties | |
Chemical formula | Fe2O3 |
Molar mass | 159.687 g·mol−1 |
Appearance | Red-brown solid |
Odor | Odorless |
Density | 5.25 g/cm3 |
Melting point | 1,539 °C (2,802 °F; 1,812 K) decomposes 105 °C (221 °F; 378 K) β-dihydrate, decomposes 150 °C (302 °F; 423 K) β-monohydrate, decomposes 50 °C (122 °F; 323 K) α-dihydrate, decomposes 92 °C (198 °F; 365 K) α-monohydrate, decomposes |
Solubility in water | Insoluble |
Solubility | Soluble in diluted acids,barely soluble in sugarsolution Trihydrate slightly soluble in aq. tartaric acid, citric acid, CH3COOH |
Magnetic susceptibility (χ) | +3586.0·10−6 cm3/mol |
Refractive index(nD) | n1=2.91, n2=3.19 (α, hematite) |
Structure | |
Crystal structure | Rhombohedral, hR30 (α-form) Cubic bixbyite, cI80 (β-form) Cubic spinel (γ-form) Orthorhombic (ε-form) |
Space group | R3c, No. 161 (α-form) Ia3, No. 206 (β-form) Pna21, No. 33 (ε-form) |
Point group | 3m (α-form) 2/m 3 (β-form) mm2 (ε-form) |
Coordination geometry | Octahedral (Fe3+, α-form, β-form) |
Hazards | |
GHS pictograms | |
GHS Signal word | Warning |
GHS hazard statements | H315, H319, H335 |
GHS precautionary statements | P261, P305+351+338 |
Threshold limit value (TLV) | 5 mg/m3 (TWA) |
Lethal dose or concentration (LD, LC): | |
LD50 (median dose) | 10 g/kg (rats, oral) |
Related compounds | |
Other anions | Iron(III) fluoride |
Other cations | Manganese(III) oxide Cobalt(III) oxide |
Related iron oxides | Iron(II) oxide Iron(II,III) oxide |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). | |
verify | |
Infobox references | |
Iron(III) oxide or ferric oxide is the inorganic compound with the formula Fe2O3. It is one of the three main oxides of iron, the other two being iron(II) oxide (FeO), which is rare; and iron(II,III) oxide (Fe3O4), which also occurs naturally as the mineral magnetite. As the mineral known as hematite, Fe2O3 is the main source of iron for the steel industry. Fe2O3 is readily attacked by acids. Iron(III) oxide is often called rust, and to some extent this label is useful, because rust shares several properties and has a similar composition; however, in chemistry, rust is considered an ill-defined material, described as Hydrous ferric oxide
Several hydrates of Iron(III) oxide exists. When alkali is added to solutions of soluble Fe(III) salts, a red-brown gelatinous precipitate forms. This is not Fe(OH)3, but Fe2O3·H2O (also written as Fe(O)OH). Several forms of the hydrated oxide of Fe(III) exist as well. The red lepidocrocite γ-Fe(O)OH, occurs on the outside of rusticles, and the orange goethite, which occurs internally in rusticles. When Fe2O3·H2O is heated, it loses its water of hydration. Further heating at 1670 K converts Fe2O3 to black Fe3O4 (FeIIFeIII2O4), which is known as the mineral magnetite. Fe(O)OH is soluble in acids, giving [Fe(H2O)6]3+. In concentrated aqueous alkali, Fe2O3 gives [Fe(OH)6]3−.
The overwhelming application of iron(III) oxide is as the feedstock of the steel and iron industries, e.g. the production of iron, steel, and many alloys.
Iron(III) oxide is also used as a pigment, under names "Pigment Brown 6", "Pigment Brown 7", and "Pigment Red 101". Some of them, e.g. Pigment Red 101 and Pigment Brown 6, are approved by the US Food and Drug Administration (FDA) for use in cosmetics. Iron oxides are used as pigments in dental composites alongside titanium oxides.
Hematite is the characteristic component of the Swedish paint color Falu red.
Magnetic recording
Iron(III) oxide was the most common magnetic particle used in all types of magnetic storage and recording media, including magnetic disks (for data storage) and magnetic tape (used in audio and video recording as well as data storage). Its use in computer disks was superseded by cobalt alloy, enabling thinner magnetic films with higher storage density.
α-Fe2O3 has been studied as a photoanode for solar water oxidation. However, its efficacy is limited by a short diffusion length (2-4 nm) of photo-excited charge carriers and subsequent fast recombination, requiring a large overpotential to drive the reaction.Research has been focused on improving the water oxidation performance of Fe2O3 using nanostructuring, surface functionalization, or by employing alternate crystal phases such as β-Fe2O3.
Calamine lotion, used to treat mild itchiness, is chiefly composed of a combination of zinc oxide, acting as astringent, and about 0.5% iron(III) oxide, the product's active ingredient, acting as antipruritic. The red color of iron(III) oxide is also mainly responsible for the lotion's pink color.
Other color of products:
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